2018-ko-che

QUESTIONS AND SOLUTIONS

 

If necessary, use the following data to answer the questions below.

Atomic Weight: H = 1.0, C = 12.0, N = 14.0, O = 16.0, S = 32.0, Cu = 64.0

Molar volume of gas at the standard state: 22.4 L/mol

Gas constant: = 0.082 atm L / (Kmol) = 8.31 × 103 Pa L/(Kmol )

Avogadro constant: A = 6.02 × 1023 /mol

Pressure: 1 atm = 1.01 × 105 Pa = 760 mmHg

Faraday constant: = 9.65 × 104 C / mol

 

Choose the correct answer from the choices to below. Select the closest one, when your calculated result does not exactly match any of the values of the alternatives in each group.

 

QUESTION 01

Which of the following elements is not the noble gas?

(A)   Ne

(B)   Ar

(C)   Br

(D)   Kr

(E)   Xe

 


QUESTION 02

Which of the following elements has the smallest electronegativity?

(A)   K

(B)   Cl

(C)   Zn

(D)   Li

(E)   O

 


QUESTION 03

Which of the following atoms has the most valence electrons?

(A)   N

(B)   S

(C)   Na

(D)   Si

(E)   F

 


QUESTION 04

Which of the following molecules has the most lone pair electrons?

(A)   \(\ce{CH3OH}\)

(B)   \(\ce{C2H4}\)

(C)   \(\ce{NH3}\)

(D)   \(\ce{CO2}\)

(E)   \(\ce{HCl}\)

 


QUESTION 05

Which of the following oxides is an amphoteric oxide?

(A)   \(\ce{NO2}\)

(B)   \(\ce{CO2}\)

(C)   \(\ce{Na2O}\)

(D)   \(\ce{CaO}\)

(E)   \(\ce{ZnO}\)

 


QUESTION 06

Which of the following compounds has the maximum mass percentage of carbon in the compound?

(A)   \(\ce{CH3CHO}\)

(B)   \(\ce{C2H5OH}\)

(C)   \(\ce{CH3OCH3}\)

(D)   \(\ce{CH3OH}\)

(E)   \(\ce{CH3OH}\)

 


QUESTION 07

The volume percentage of hydrogen, \(\ce{H2}\), gas is 30% in a mixture of hydrogen gas and methane, \(\ce{CH4}\), gas at the standard state.

Answer the following questions.

(1)   Calculate the density of the mixed gas.

(A)   0.28 g/L

(B)   0.53 g/L

(C)   2.8 g/L

(D)   5.3 g/L

(E)   28 g/L

 

(2)   Calculate the heat evolved in a complete combustion of 10.0 L of the mixed gas at the standard state. The heats of combustion of hydrogen and methane are 286 and 891 kJ/mol, respectively.

(A)   103 kJ

(B)   209 kJ

(C)   317 kJ

(D)   421 kJ

(E)   533 kJ

 


QUESTION 08

The density of 17.0% sulfuric acid, \(\ce{H2SO4}\), is 1.12 g/mL. Calculate the molar concentration of the sulfuric acid.

(A)   0.9 mol/L

(B)   1.9 mol/L

(C)   2.9 mol/L

(D)   3.9 mol/L

(E)   4.9 mol/L

 


QUESTION 09

The solubilities of copper (II) sulfate, \(\ce{CuSO4}\), in water are 20 [g/100 g \(\ce{H2O}\)] at 293 K, and 54 [g/100 g \(\ce{H2O}\)] at 353 K. How many grams of copper (II) sulfate pentahydrate, \(\ce{CuSO4 5H2O}\), will crystallize out of 200 g of a solution saturated at 353 K if it cools to 293 K?

(A)   32 g

(B)   41 g

(C)   55 g

(D)   64 g

(E)   77 g

 


QUESTION 10

Calculate the degree of ionization, \(\alpha\), of \(1.0 \times 10^{-2} \text{ mol/L}\) acetic acid, \(\ce{CH3COOH}\). The ionization constant, Ka, of acetic acid is \(2.7 \times 10^{-5} \text{ mol/L}\). Use the following value, if necessary.

\(\sqrt{3} = 1.73\)

(A)   0.017

(B)   0.026

(C)   0.035

(D)   0.043

(E)   0.052

 


QUESTION 11

The mass of oxygen, \(\ce{O2}\), gas occupied a volume of 550 mL is 0.96 g at 330 K. Calculate the pressure of the oxygen gas.

 


QUESTION 12

In the following reaction, which of the following procedures is correct for the displacement of the equilibrium in the right direction?

\(\ce{N2 + 3 H2 <=> 2 NH3 + 92 kJ}\)

 


QUESTION 13

A certain amount of oxalic acid, \(\ce{(COOH)2}\), reacted with 200 mL of 0.020 mol/L potassium permanganate, \(\ce{KMnO4}\), to oxidize completely. Calculate the mass of the oxalic acid.

 


QUESTION 14

When electrolysis of a sulfuric acid, \(\ce{H2SO4}\), was carried out at 2.0 A for 25 min using a platinum, \(\ce{Pt}\), electrode, oxygen, \(\ce{O2}\), gas was liberated. Calculate the volume of the oxygen gas at the standard state.

 


QUESTION 15

Which of the following gases is the colored gas?

 


QUESTION 16

Which of the following metal complex ion solutions is the colored solution?

 


QUESTION 17

How many isomers are there for the compound with molecular formula \(\ce{C2H4O}\)?

 


QUESTION 18

Which of the following molecules has a positive reaction in the Fehling’s solution test?

 

QUESTION 19

Which of the following molecules does not react with ethylene \(\ce{CH2=CH2}\)?

 


Next